{"id":342,"date":"2025-11-20T11:06:16","date_gmt":"2025-11-20T11:06:16","guid":{"rendered":"https:\/\/poisonshops.com\/?post_type=product&p=342"},"modified":"2025-12-02T15:32:34","modified_gmt":"2025-12-02T15:32:34","slug":"%e3%83%8b%e3%83%83%e3%82%b1%e3%83%ab%e3%82%ab%e3%83%ab%e3%83%9c%e3%83%8b%e3%83%ab","status":"publish","type":"product","link":"https:\/\/poisonshops.com\/ja\/%e8%a3%bd%e5%93%81\/%e3%83%8b%e3%83%83%e3%82%b1%e3%83%ab%e3%82%ab%e3%83%ab%e3%83%9c%e3%83%8b%e3%83%ab\/","title":{"rendered":"\u30cb\u30c3\u30b1\u30eb\u30ab\u30eb\u30dc\u30cb\u30eb"},"content":{"rendered":"

\u30cb\u30c3\u30b1\u30eb\u30ab\u30eb\u30dc\u30cb\u30eb\u3092\u30aa\u30f3\u30e9\u30a4\u30f3\u3067\u8cfc\u5165<\/h2>\n

\u30cb\u30c3\u30b1\u30eb\u30ab\u30eb\u30dc\u30cb\u30eb\u3068\u306f\u4f55\u304b<\/h4>\n

\u30cb\u30c3\u30b1\u30eb\u30ab\u30eb\u30dc\u30cb\u30eb\u3092\u30aa\u30f3\u30e9\u30a4\u30f3\u3067\u8cfc\u5165<\/a> \uff08IUPAC\u540d\uff1a\u30c6\u30c8\u30e9\u30ab\u30eb\u30dc\u30cb\u30eb\u30cb\u30c3\u30b1\u30eb\uff09\u306f\u3001\u5316\u5b66\u5f0f Ni(CO)\u2084 \u3092\u6709\u3059\u308b\u6709\u6a5f\u30cb\u30c3\u30b1\u30eb\u5316\u5408\u7269\u3067\u3042\u308b\u3002\u3053\u306e\u7121\u8272\u306e\u6db2\u4f53\u306f\u3001\u30cb\u30c3\u30b1\u30eb\u306e\u4e3b\u8981\u306a\u30ab\u30eb\u30dc\u30cb\u30eb\u5316\u5408\u7269\u3067\u3042\u308b\u3002.<\/p>\n

\u3053\u308c\u306f\u3001\u8d85\u9ad8\u7d14\u5ea6\u30ab\u30eb\u30dc\u30cb\u30eb\u30cb\u30c3\u30b1\u30eb\u3092\u88fd\u9020\u3059\u308b\u30e2\u30f3\u30c9\u6cd5\u306b\u304a\u3051\u308b\u4e2d\u9593\u4f53\u3067\u3042\u308a\u3001\u6709\u6a5f\u91d1\u5c5e\u5316\u5b66\u306b\u304a\u3051\u308b\u8a66\u85ac\u3067\u3082\u3042\u308b\u3002\u305f\u3060\u3057\u3001\u3053\u306e\u5316\u5408\u7269\u306e\u53d6\u308a\u6271\u3044\u306b\u304a\u3051\u308b\u5065\u5eb7\u88ab\u5bb3\u306e\u305f\u3081\u3001\u30e2\u30f3\u30c9\u6cd5\u306f\u73fe\u5728\u3067\u306f\u4e00\u822c\u7684\u3067\u306f\u306a\u304f\u306a\u3063\u3066\u3044\u308b\u3002.<\/p>\n

\u30cb\u30c3\u30b1\u30eb\u30ab\u30eb\u30dc\u30cb\u30eb\u306f\u3001\u6975\u3081\u3066\u9ad8\u3044\u6bd2\u6027\u306b\u52a0\u3048\u3001\u9ad8\u3044\u63ee\u767a\u6027\u3068\u76ae\u819a\u304b\u3089\u306e\u6025\u901f\u306a\u5438\u53ce\u3092\u4f75\u305b\u6301\u3064\u305f\u3081\u3001\u30cb\u30c3\u30b1\u30eb\u5316\u5b66\u306b\u304a\u3044\u3066\u3053\u308c\u307e\u3067\u906d\u9047\u3057\u305f\u4e2d\u3067\u3082\u6700\u3082\u5371\u967a\u306a\u7269\u8cea\u306e\u4e00\u3064\u3067\u3042\u308b\u3002\u95c7\u5e02\u5834\u3067\u30cb\u30c3\u30b1\u30eb\u30ab\u30eb\u30dc\u30cb\u30eb\u3092\u8cfc\u5165\u305b\u3088\u3002.<\/p>\n

\"\u6bd2\u5c4b\"<\/p>\n

\u69cb\u9020\u3068\u7d50\u5408<\/span><\/h2>\n

\u30cb\u30c3\u30b1\u30eb\u30c6\u30c8\u30e9\u30ab\u30eb\u30dc\u30cb\u30eb\u306b\u304a\u3044\u3066\u3001\u30cb\u30c3\u30b1\u30eb\u306e\u9178\u5316\u6570\u306f0\u3068\u5272\u308a\u5f53\u3066\u3089\u308c\u308b\u3002\u3053\u306e\u5f0f\u306f18\u96fb\u5b50\u5247\u306b\u9069\u5408\u3059\u308b\u3002 \u3053\u306e\u5206\u5b50\u306f\u56db\u9762\u4f53\u69cb\u9020\u3092\u3068\u308a\u30014\u3064\u306e\u30ab\u30eb\u30dc\u30cb\u30eb\uff08\u4e00\u9178\u5316\u70ad\u7d20\uff09\u914d\u4f4d\u5b50\u3092\u6709\u3059\u308b\u3002\u96fb\u5b50\u56de\u6298\u6cd5\u306b\u3088\u308b\u7814\u7a76\u304c\u884c\u308f\u308c\u3001Ni\u2013C\u7d50\u5408\u9577\u3068C\u2013O\u7d50\u5408\u9577\u306f\u305d\u308c\u305e\u308c1.838(2)\u30aa\u30f3\u30b0\u30b9\u30c8\u30ed\u30fc\u30e0\u30011.141(2)\u30aa\u30f3\u30b0\u30b9\u30c8\u30ed\u30fc\u30e0\u3068\u7b97\u51fa\u3055\u308c\u305f\u3002\u30cb\u30c3\u30b1\u30eb\u30ab\u30eb\u30dc\u30cb\u30eb\u3092\u30aa\u30f3\u30e9\u30a4\u30f3\u3067\u8cfc\u5165\u3002.<\/p>\n

\u6e96\u5099<\/span><\/h3>\n

\u30cb(CO)\u2084\u306f1890\u5e74\u3001\u30eb\u30fc\u30c8\u30f4\u30a3\u30d2\u30fb\u30e2\u30f3\u30c9\u306b\u3088\u3063\u3066\u30cb\u30c3\u30b1\u30eb\u91d1\u5c5e\u3068\u4e00\u9178\u5316\u70ad\u7d20\u306e\u76f4\u63a5\u53cd\u5fdc\u306b\u3088\u308a\u521d\u3081\u3066\u5408\u6210\u3055\u308c\u305f\u3002\u3053\u306e\u5148\u99c6\u7684\u306a\u7814\u7a76\u306f\u3001\u4e94\u4fa1\u306e\u30cb\u30c3\u30b1\u30eb\u3001\u30af\u30ed\u30e0\u3001\u30de\u30f3\u30ac\u30f3\u3001\u9244\u3001\u30b3\u30d0\u30eb\u30c8\u3092\u542b\u3080\u591a\u304f\u306e\u91d1\u5c5e\u30ab\u30eb\u30dc\u30cb\u30eb\u5316\u5408\u7269\u306e\u5b58\u5728\u3092\u4e88\u898b\u3059\u308b\u3082\u306e\u3067\u3042\u3063\u305f\u3002\u307e\u305f19\u4e16\u7d00\u672b\u307e\u3067\u306b\u3001\u30cb\u30c3\u30b1\u30eb\u7cbe\u88fd\u3078\u306e\u5de5\u696d\u7684\u5fdc\u7528\u3082\u5b9f\u73fe\u3057\u305f\u3002.<\/p>\n

323 K\uff0850 \u00b0C; 122 \u00b0F\uff09\u3067\u4e00\u9178\u5316\u70ad\u7d20\u3092\u4e0d\u7d14\u30cb\u30c3\u30b1\u30eb\u306b\u901a\u3059\u3002\u6700\u9069\u53cd\u5fdc\u901f\u5ea6\u306f130 \u00b0C\u3067\u767a\u751f\u3059\u308b\u3002\u95c7\u5e02\u5834\u3067\u30cb\u30c3\u30b1\u30eb\u30ab\u30eb\u30dc\u30cb\u30eb\u3092\u8cfc\u5165\u305b\u3088\u3002.<\/p>\n

\u71b1\u8131\u70ad\u9178<\/span><\/h4>\n

\u4e2d\u7a0b\u5ea6\u306e\u52a0\u71b1\u4e0b\u3067\u3001Ni(CO)4<\/sub> \u4e00\u9178\u5316\u70ad\u7d20\u3068\u30cb\u30c3\u30b1\u30eb\u91d1\u5c5e\u306b\u5206\u89e3\u3059\u308b\u3002\u4e00\u9178\u5316\u70ad\u7d20\u304b\u3089\u306e\u751f\u6210\u304c\u5bb9\u6613\u3067\u3042\u308b\u3053\u3068\u3001\u3055\u3089\u306b\u306f\u4e0d\u7d14\u5ea6\u306e\u9ad8\u3044\u30cb\u30c3\u30b1\u30eb\u304b\u3089\u3082\u751f\u6210\u3055\u308c\u308b\u3053\u3068\u306b\u52a0\u3048\u3001\u3053\u306e\u5206\u89e3\u7279\u6027\u304c\u3001\u30cb\u30c3\u30b1\u30eb\u30ab\u30eb\u30dc\u30cb\u30eb\u306e\u7cbe\u88fd\u3084\u8868\u9762\u3081\u3063\u304d\u3092\u76ee\u7684\u3068\u3057\u305f\u30e2\u30f3\u30c9\u6cd5\u306e\u57fa\u790e\u3068\u306a\u3063\u3066\u3044\u308b\u3002\u71b1\u5206\u89e3\u306f\u7d04180\u2103\u4ed8\u8fd1\u3067\u59cb\u307e\u308a\u3001\u9ad8\u6e29\u306b\u306a\u308b\u307b\u3069\u9032\u884c\u3059\u308b\u3002.<\/p>\n

\"\u751f\u7269\u5175\u5668\"<\/p>\n

\u30cb\u30c3\u30b1\u30eb\u30ab\u30eb\u30dc\u30cb\u30eb\u3092\u30aa\u30f3\u30e9\u30a4\u30f3\u3067\u8cfc\u5165\u3059\u308b<\/h3>\n

\u6c42\u96fb\u5b50\u5264\u304a\u3088\u3073\u9178\u5316\u5264\u3068\u306e\u53cd\u5fdc<\/span><\/h5>\n

\u30cb\u30c3\u30b1\u30eb\u30ab\u30eb\u30dc\u30cb\u30eb\u306f\u9178\u5316\u3055\u308c\u308b\u3002\u5869\u7d20\u306f\u30cb\u30c3\u30b1\u30eb\u30ab\u30eb\u30dc\u30cb\u30eb\u3092NiCl\u2083\u306b\u9178\u5316\u3059\u308b\u30022<\/sub>, \u30cf\u30ed\u30b2\u30f3\u5316\u7269\u306b\u6c34\u9178\u5316\u30ca\u30c8\u30ea\u30a6\u30e0\u3092\u6dfb\u52a0\u3059\u308b\u3068\u3001CO\u30ac\u30b9\u3092\u653e\u51fa\u3057\u306a\u304c\u3089\u30cb\u30c3\u30b1\u30eb\u5869\u3092\u751f\u6210\u3059\u308b\u3002\u4ed6\u306e\u30cf\u30ed\u30b2\u30f3\u3082\u540c\u69d8\u306e\u6319\u52d5\u3092\u793a\u3059\u3002\u3053\u306e\u53cd\u5fdc\u306f\u3001\u6709\u6bd2\u5316\u5408\u7269\u306e\u30cb\u30c3\u30b1\u30eb\u90e8\u5206\u3092\u6c88\u6bbf\u3055\u305b\u308b\u4fbf\u5229\u306a\u65b9\u6cd5\u3092\u63d0\u4f9b\u3059\u308b\u3002.<\/p>\n

Ni(CO)\u306e\u53cd\u5fdc4<\/sub> \u30a2\u30eb\u30ad\u30eb\u304a\u3088\u3073\u30a2\u30ea\u30fc\u30eb\u30cf\u30ed\u30b2\u30f3\u5316\u7269\u3068\u306e\u53cd\u5fdc\u306f\u3001\u3057\u3070\u3057\u3070\u30ab\u30eb\u30dc\u30cb\u30eb\u5316\u6709\u6a5f\u751f\u6210\u7269\u3092\u751f\u3058\u3055\u305b\u308b\u3002.<\/p>\n

\u5869\u5316\u30d3\u30cb\u30eb\u57fa\u3092\u6709\u3059\u308b\u5316\u5408\u7269\uff08\u4f8b\uff1aPhCH=CHBr\uff09\u306f\u3001Ni(CO)\u2082\u51e6\u7406\u306b\u3088\u308a\u4e0d\u98fd\u548c\u30a8\u30b9\u30c6\u30eb\u3078\u3068\u5909\u63db\u3055\u308c\u308b\u30024<\/sub> \u7d9a\u3044\u3066\u30ca\u30c8\u30ea\u30a6\u30e0\u30e1\u30c8\u30ad\u30b7\u30c9\u3092\u52a0\u3048\u308b\u3002.<\/p>\n

\u3053\u306e\u3088\u3046\u306a\u53cd\u5fdc\u3082\u304a\u305d\u3089\u304f\u9178\u5316\u4ed8\u52a0\u3092\u4ecb\u3057\u3066\u9032\u884c\u3059\u308b\u3002\u30a2\u30ea\u30eb\u30cf\u30ed\u30b2\u30f3\u5316\u7269\u306f\uff08\u30a2\u30ea\u30eb\uff09\u30cb\u30c3\u30b1\u30eb\u306a\u3069\u306e\u03c0-\u30a2\u30ea\u30eb\u30cb\u30c3\u30b1\u30eb\u5316\u5408\u7269\u3092\u751f\u6210\u3059\u308b\u30022<\/sub>\u30cb2<\/sub>Cl2<\/sub>:<\/p>\n

\n
2 Ni(CO)4<\/sub>\u00a0+ 2 ClCH2<\/sub>CH=CH2<\/sub>\u00a0\u2192 \u30cb2<\/sub>(\u03bc<\/i>-Cl)2<\/sub>(\u03b7<\/i>3<\/sup>-C3<\/sub>H5<\/sub>)2<\/sub>\u00a0+ 8 CO<\/dd>\n<\/dl>\n

\"\u6bd2\u7269\u5e97\"<\/p>","protected":false},"excerpt":{"rendered":"

Melting point: :<\/b>-19\u00b0C
\nBoiling point: :<\/b>43\u00b0C
\nDensity\u00a0 :<\/b>1,32 g\/cm3<\/sup>
\nvapor pressure\u00a0 :<\/b>321 mmHg at 20 \u00b0C
\nFlash point: :<\/b><-20\u00b0C
\nform\u00a0 :<\/b>liquid
\ncolor\u00a0 :<\/b>colorless
\nOdor :<\/b>Sooty odor detectable at 0.5 to 3 ppm
\nWater Solubility\u00a0 :<\/b>soluble in ~5000 parts air free H2O; soluble alcohol, benzene, chloroform, acetone, CCl4 [MER06]
\nSensitive\u00a0 :<\/b>heat sensitive
\nExposure limits :<\/b>TLV-TWA: 0.05 ppm (0.35 mg as Ni\/m3<\/sup>) (ACGIH)
\nPEL: 0.001 ppm (0.007 mg Ni\/m3<\/sup>) (OSHA, MSHA and NIOSH)
\nIDLH: 0.001 ppm (NIOSH, OSHA).\u00a0Stability: :<\/b>Stable. Highly flammable and highly reactive. Explosion hazard.
\nEPA Substance Registry System :<\/b>Nickel carbonyl (13463-39-3)<\/p>\n","protected":false},"featured_media":343,"comment_status":"open","ping_status":"closed","template":"","meta":[],"product_brand":[],"product_cat":[17],"product_tag":[],"class_list":{"0":"post-342","1":"product","2":"type-product","3":"status-publish","4":"has-post-thumbnail","6":"product_cat-poisons-for-sale","8":"first","9":"instock","10":"shipping-taxable","11":"purchasable","12":"product-type-variable"},"_links":{"self":[{"href":"https:\/\/poisonshops.com\/ja\/wp-json\/wp\/v2\/product\/342","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/poisonshops.com\/ja\/wp-json\/wp\/v2\/product"}],"about":[{"href":"https:\/\/poisonshops.com\/ja\/wp-json\/wp\/v2\/types\/product"}],"replies":[{"embeddable":true,"href":"https:\/\/poisonshops.com\/ja\/wp-json\/wp\/v2\/comments?post=342"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/poisonshops.com\/ja\/wp-json\/wp\/v2\/media\/343"}],"wp:attachment":[{"href":"https:\/\/poisonshops.com\/ja\/wp-json\/wp\/v2\/media?parent=342"}],"wp:term":[{"taxonomy":"product_brand","embeddable":true,"href":"https:\/\/poisonshops.com\/ja\/wp-json\/wp\/v2\/product_brand?post=342"},{"taxonomy":"product_cat","embeddable":true,"href":"https:\/\/poisonshops.com\/ja\/wp-json\/wp\/v2\/product_cat?post=342"},{"taxonomy":"product_tag","embeddable":true,"href":"https:\/\/poisonshops.com\/ja\/wp-json\/wp\/v2\/product_tag?post=342"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}