{"id":342,"date":"2025-11-20T11:06:16","date_gmt":"2025-11-20T11:06:16","guid":{"rendered":"https:\/\/poisonshops.com\/?post_type=product&p=342"},"modified":"2025-12-02T15:32:34","modified_gmt":"2025-12-02T15:32:34","slug":"%eb%8b%88%ec%bc%88-%ec%b9%b4%eb%a5%b4%eb%b3%b4%eb%8b%90","status":"publish","type":"product","link":"https:\/\/poisonshops.com\/ko\/%ec%a0%9c%ed%92%88\/%eb%8b%88%ec%bc%88-%ec%b9%b4%eb%a5%b4%eb%b3%b4%eb%8b%90\/","title":{"rendered":"\ub2c8\ucf08 \uce74\ubcf4\ub2d0"},"content":{"rendered":"

\ub2c8\ucf08 \uce74\ubcf4\ub2d0 \uc628\ub77c\uc778 \uad6c\ub9e4<\/h2>\n

\ub2c8\ucf08 \uce74\ubcf4\ub2d0\uc774\ub780?<\/h4>\n

\ub2c8\ucf08 \uce74\ubcf4\ub2d0 \uc628\ub77c\uc778 \uad6c\ub9e4<\/a> (IUPAC \uba85\uce6d: \ud14c\ud2b8\ub77c\uce74\ubcf4\ub2d0\ub2c8\ucf08)\uc740 \ud654\ud559\uc2dd Ni(CO)4\uc758 \uc720\uae30\ub2c8\ucf08 \ud654\ud569\ubb3c\ub85c, \ubb34\uc0c9\uc758 \uc561\uccb4\ub85c \ub2c8\ucf08\uc758 \uc8fc\uc694 \uce74\ub974\ubcf4\ub2d0\uc785\ub2c8\ub2e4.<\/p>\n

\ubaac\ub4dc \uacf5\uc815\uc740 \ud654\ud569\ubb3c \uc791\uc5c5\uc758 \uac74\uac15 \uc704\ud5d8\uc73c\ub85c \uc778\ud574 \uc77c\ubc18\uc801\uc73c\ub85c \uc0ac\uc6a9\ub418\uc9c0 \uc54a\uc9c0\ub9cc \ub9e4\uc6b0 \uace0\uc21c\ub3c4 \ub2c8\ucf08 \uce74\ubcf4\ub2d0 \uc628\ub77c\uc778 \uad6c\ub9e4 \ubc0f \uc720\uae30 \uae08\uc18d \ud654\ud559\uc758 \uc2dc\uc57d\uc744 \uc0dd\uc0b0\ud558\uae30\uc704\ud55c \ubaac\ub4dc \uacf5\uc815\uc758 \uc911\uac04\uccb4\uc785\ub2c8\ub2e4.<\/p>\n

\ub2c8\ucf08 \uce74\ubcf4\ub2d0\uc740 \ub2c8\ucf08 \ud654\ud559\uc5d0\uc11c \uac00\uc7a5 \uc704\ud5d8\ud55c \ubb3c\uc9c8 \uc911 \ud558\ub098\ub85c, \ub3c5\uc131\uc774 \ub9e4\uc6b0 \ub192\uace0 \ud718\ubc1c\uc131\uc774 \ub192\uc73c\uba70 \ud53c\ubd80 \ud761\uc218\uac00 \ube60\ub974\uae30 \ub54c\ubb38\uc785\ub2c8\ub2e4. \uc554\uc2dc\uc7a5\uc5d0\uc11c \ub2c8\ucf08 \uce74\ubcf4\ub2d0\uc744 \uad6c\ub9e4\ud558\uc138\uc694.<\/p>\n

\"\ub3c5\uc57d<\/p>\n

\uad6c\uc870 \ubc0f \uacb0\ud569<\/span><\/h2>\n

\ub2c8\ucf08 \ud14c\ud2b8\ub77c\uce74\ubcf4\ub2d0\uc5d0\uc11c \ub2c8\ucf08\uc758 \uc0b0\ud654 \uc0c1\ud0dc\ub294 0\uc73c\ub85c \uc9c0\uc815\ub429\ub2c8\ub2e4. \uc774 \uacf5\uc2dd\uc740 18\uc804\uc790 \uaddc\uce59\uc744 \ub530\ub985\ub2c8\ub2e4. \uc774 \ubd84\uc790\ub294 \uc0ac\uba74\uccb4\uc774\uba70 4\uac1c\uc758 \uce74\ub974\ubcf4\ub2d0(\uc77c\uc0b0\ud654\ud0c4\uc18c) \ub9ac\uac04\ub4dc\ub97c \uac00\uc9c0\uace0 \uc788\uc2b5\ub2c8\ub2e4. \uc774 \ubd84\uc790\uc5d0 \ub300\ud55c \uc804\uc790 \ud68c\uc808 \uc5f0\uad6c\ub97c \uc218\ud589\ud55c \uacb0\uacfc, Ni-C \ubc0f C-O \uac70\ub9ac\ub294 \uac01\uac01 1.838(2) \ubc0f 1.141(2) \uc639\uc2a4\ud2b8\ub86c\uc73c\ub85c \uacc4\uc0b0\ub418\uc5c8\uc2b5\ub2c8\ub2e4. \ub2c8\ucf08 \uce74\ubcf4\ub2d0 \uc628\ub77c\uc778 \uad6c\ub9e4.<\/p>\n

\uc900\ube44<\/span><\/h3>\n

Ni(CO)4\ub294 1890\ub144 \ub8e8\ub4dc\ube44\ud788 \ubaac\ub4dc\uac00 \ub2c8\ucf08 \uae08\uc18d\uacfc CO\uc758 \uc9c1\uc811 \ubc18\uc751\uc744 \ud1b5\ud574 \ucc98\uc74c \ud569\uc131\ud588\uc2b5\ub2c8\ub2e4. \uc774 \uc120\uad6c\uc801\uc778 \uc5f0\uad6c\ub294 V, Cr, Mn, Fe, Co\ub97c \ud3ec\ud568\ud55c \ub2e4\ub978 \ub9ce\uc740 \uae08\uc18d \uce74\ub974\ubcf4\ub2d0 \ud654\ud569\ubb3c\uc758 \uc874\uc7ac\ub97c \uc608\uace0\ud588\uc2b5\ub2c8\ub2e4. \ub610\ud55c 19\uc138\uae30 \ub9d0\uc5d0\ub294 \ub2c8\ucf08\uc758 \uc815\uc81c\uc5d0 \uc0b0\uc5c5\uc801\uc73c\ub85c \uc801\uc6a9\ub418\uc5c8\uc2b5\ub2c8\ub2e4.<\/p>\n

323\u00b0C(50\u00b0F, 122\u00b0C)\uc5d0\uc11c \uc77c\uc0b0\ud654\ud0c4\uc18c\ub294 \ubd88\uc21c\ubb3c\uc778 \ub2c8\ucf08\uc744 \ud1b5\uacfc\ud569\ub2c8\ub2e4. \ucd5c\uc801\uc758 \ube44\uc728\uc740 130\u00b0C\uc5d0\uc11c \ubc1c\uc0dd\ud569\ub2c8\ub2e4. \uc554\uc2dc\uc7a5\uc5d0\uc11c \ub2c8\ucf08 \uce74\ubcf4\ub2d0\uc744 \uad6c\uc785\ud558\uc138\uc694.<\/p>\n

\uc5f4 \ud0c8\ud0c4\ud654<\/span><\/h4>\n

\uc911\uac04 \uc815\ub3c4\uc758 \uac00\uc5f4\uc5d0\uc11c Ni(CO)4<\/sub> \uc77c\uc0b0\ud654\ud0c4\uc18c\uc640 \ub2c8\ucf08 \uae08\uc18d\uc73c\ub85c \ubd84\ud574\ub429\ub2c8\ub2e4. \uc774 \ubd84\ud574\ub294 CO \ubc0f \ub9e4\uc6b0 \ubd88\uc21c\ud55c \ub2c8\ucf08\uc5d0\uc11c \uc27d\uac8c \ud615\uc131\ub418\ub294 \uac83\uacfc \uacb0\ud569\ud558\uc5ec \ub2c8\ucf08 \uce74\ubcf4\ub2d0 \uc628\ub77c\uc778 \uad6c\ub9e4 \ub610\ub294 \ud45c\uba74 \ub3c4\uae08\uc744\uc704\ud55c Mond \uacf5\uc815\uc758 \uae30\ucd08\uac00\ub429\ub2c8\ub2e4. \uc5f4\ubd84\ud574\ub294 180\u00b0C \uadfc\ucc98\uc5d0\uc11c \uc2dc\uc791\ub418\uc5b4 \ub354 \ub192\uc740 \uc628\ub3c4\uc5d0\uc11c \uc99d\uac00\ud569\ub2c8\ub2e4.<\/p>\n

\"\uc0dd\ubb3c\ud559<\/p>\n

\ub2c8\ucf08 \uce74\ubcf4\ub2d0 \uc628\ub77c\uc778 \uad6c\ub9e4<\/h3>\n

\uce5c\uc720\uc804\uc131 \ubc0f \uc0b0\ud654\uc81c\uc640\uc758 \ubc18\uc751<\/span><\/h5>\n

\ub2c8\ucf08 \uce74\ub974\ubcf4\ub2d0\uc740 \uc0b0\ud654\ub420 \uc218 \uc788\uc2b5\ub2c8\ub2e4. \uc5fc\uc18c\ub294 \ub2c8\ucf08 \uce74\ub974\ubcf4\ub2d0\uc744 \uc0b0\ud654\uc2dc\ucf1c NiCl\ub85c \ub9cc\ub4ed\ub2c8\ub2e4.2<\/sub>, \ub97c \ubc29\ucd9c\ud558\uc5ec CO \uac00\uc2a4\ub97c \ubc29\ucd9c\ud569\ub2c8\ub2e4. \ub2e4\ub978 \ud560\ub85c\uac90\ub3c4 \uc774\uc640 \uc720\uc0ac\ud558\uac8c \uc791\ub3d9\ud569\ub2c8\ub2e4. \uc774 \ubc18\uc751\uc740 \ub3c5\uc131 \ud654\ud569\ubb3c\uc758 \ub2c8\ucf08 \ubd80\ubd84\uc744 \uce68\uc804\uc2dc\ud0a4\ub294 \ud3b8\ub9ac\ud55c \ubc29\ubc95\uc744 \uc81c\uacf5\ud569\ub2c8\ub2e4.<\/p>\n

Ni(CO)\uc758 \ubc18\uc7514<\/sub> \ub97c \uc54c\ud0ac \ubc0f \uc544\ub9b4 \ud560\ub77c\uc774\ub4dc\uc640 \ud568\uaed8 \uc0ac\uc6a9\ud558\uba74 \uc885\uc885 \ud0c4\ud654 \uc720\uae30\ubb3c\uc774 \uc0dd\uc131\ub429\ub2c8\ub2e4.<\/p>\n

PhCH=CHBr\uacfc \uac19\uc740 \ube48\ub2d0 \ud560\ub77c\uc774\ub4dc\ub294 Ni(CO)\ub85c \ucc98\ub9ac\ud558\uba74 \ubd88\ud3ec\ud654 \uc5d0\uc2a4\ud14c\ub974\ub85c \uc804\ud658\ub429\ub2c8\ub2e4.4<\/sub> \uba54\ud1a1\uc0b0\ub098\ud2b8\ub968\uc774 \uadf8 \ub4a4\ub97c \uc787\uc2b5\ub2c8\ub2e4.<\/p>\n

\uc774\ub7ec\ud55c \ubc18\uc751\uc740 \uc544\ub9c8\ub3c4 \uc0b0\ud654\uc801 \ucca8\uac00\ub97c \ud1b5\ud574 \uc9c4\ud589\ub420 \uac83\uc785\ub2c8\ub2e4. \uc54c\ub9b4 \ud560\ub77c\uc774\ub4dc\ub294 (\uc54c\ub9b4)\uacfc \uac19\uc740 \u03c0-\uc54c\ub9b4\ub2c8\ucf08 \ud654\ud569\ubb3c\uc744 \uc0dd\uc131\ud569\ub2c8\ub2e4.2<\/sub>Ni2<\/sub>Cl2<\/sub>:<\/p>\n

\n
2 Ni(CO)4<\/sub>\u00a0+ 2 ClCH2<\/sub>CH=CH2<\/sub>\u00a0\u2192 Ni2<\/sub>(\u03bc<\/i>-Cl)2<\/sub>(\u03b7<\/i>3<\/sup>-C3<\/sub>H5<\/sub>)2<\/sub>\u00a0+ 8 CO<\/dd>\n<\/dl>\n

\"\ub3c5\uc57d<\/p>","protected":false},"excerpt":{"rendered":"

Melting point: :<\/b>-19\u00b0C
\nBoiling point: :<\/b>43\u00b0C
\nDensity\u00a0 :<\/b>1,32 g\/cm3<\/sup>
\nvapor pressure\u00a0 :<\/b>321 mmHg at 20 \u00b0C
\nFlash point: :<\/b><-20\u00b0C
\nform\u00a0 :<\/b>liquid
\ncolor\u00a0 :<\/b>colorless
\nOdor :<\/b>Sooty odor detectable at 0.5 to 3 ppm
\nWater Solubility\u00a0 :<\/b>soluble in ~5000 parts air free H2O; soluble alcohol, benzene, chloroform, acetone, CCl4 [MER06]
\nSensitive\u00a0 :<\/b>heat sensitive
\nExposure limits :<\/b>TLV-TWA: 0.05 ppm (0.35 mg as Ni\/m3<\/sup>) (ACGIH)
\nPEL: 0.001 ppm (0.007 mg Ni\/m3<\/sup>) (OSHA, MSHA and NIOSH)
\nIDLH: 0.001 ppm (NIOSH, OSHA).\u00a0Stability: :<\/b>Stable. Highly flammable and highly reactive. Explosion hazard.
\nEPA Substance Registry System :<\/b>Nickel carbonyl (13463-39-3)<\/p>\n","protected":false},"featured_media":343,"comment_status":"open","ping_status":"closed","template":"","meta":[],"product_brand":[],"product_cat":[17],"product_tag":[],"class_list":{"0":"post-342","1":"product","2":"type-product","3":"status-publish","4":"has-post-thumbnail","6":"product_cat-poisons-for-sale","8":"first","9":"instock","10":"shipping-taxable","11":"purchasable","12":"product-type-variable"},"_links":{"self":[{"href":"https:\/\/poisonshops.com\/ko\/wp-json\/wp\/v2\/product\/342","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/poisonshops.com\/ko\/wp-json\/wp\/v2\/product"}],"about":[{"href":"https:\/\/poisonshops.com\/ko\/wp-json\/wp\/v2\/types\/product"}],"replies":[{"embeddable":true,"href":"https:\/\/poisonshops.com\/ko\/wp-json\/wp\/v2\/comments?post=342"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/poisonshops.com\/ko\/wp-json\/wp\/v2\/media\/343"}],"wp:attachment":[{"href":"https:\/\/poisonshops.com\/ko\/wp-json\/wp\/v2\/media?parent=342"}],"wp:term":[{"taxonomy":"product_brand","embeddable":true,"href":"https:\/\/poisonshops.com\/ko\/wp-json\/wp\/v2\/product_brand?post=342"},{"taxonomy":"product_cat","embeddable":true,"href":"https:\/\/poisonshops.com\/ko\/wp-json\/wp\/v2\/product_cat?post=342"},{"taxonomy":"product_tag","embeddable":true,"href":"https:\/\/poisonshops.com\/ko\/wp-json\/wp\/v2\/product_tag?post=342"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}