{"id":342,"date":"2025-11-20T11:06:16","date_gmt":"2025-11-20T11:06:16","guid":{"rendered":"https:\/\/poisonshops.com\/?post_type=product&p=342"},"modified":"2025-12-02T15:32:34","modified_gmt":"2025-12-02T15:32:34","slug":"%e7%be%b0%e5%9f%ba%e9%95%8d","status":"publish","type":"product","link":"https:\/\/poisonshops.com\/zh\/%e4%ba%a7%e5%93%81\/%e7%be%b0%e5%9f%ba%e9%95%8d\/","title":{"rendered":"\u78b3\u954d"},"content":{"rendered":"

\u5728\u7ebf\u8d2d\u4e70\u78b3\u954d<\/h2>\n

\u4ec0\u4e48\u662f\u954d\u7fb0\u57fa<\/h4>\n

\u5728\u7ebf\u8d2d\u4e70\u78b3\u954d<\/a> \uff08IUPAC\u540d\u79f0\uff1a\u56db\u7fb0\u57fa\u954d\uff09\u662f\u4e00\u79cd\u6709\u673a\u954d\u5316\u5408\u7269\uff0c\u5316\u5b66\u5f0f\u4e3aNi(CO)\u2084\u3002\u8fd9\u79cd\u65e0\u8272\u6db2\u4f53\u662f\u954d\u7684\u4e3b\u8981\u7fb0\u57fa\u5316\u5408\u7269\u3002.<\/p>\n

\u5b83\u65e2\u662f\u8499\u5fb7\u6cd5\u751f\u4ea7\u8d85\u9ad8\u7eaf\u5ea6\u78b3\u954d\u7684\u4e2d\u95f4\u4f53\uff0c\u4e5f\u662f\u6709\u673a\u91d1\u5c5e\u5316\u5b66\u4e2d\u7684\u8bd5\u5242\u3002\u4e0d\u8fc7\u7531\u4e8e\u64cd\u4f5c\u8be5\u5316\u5408\u7269\u5b58\u5728\u5065\u5eb7\u98ce\u9669\uff0c\u8499\u5fb7\u6cd5\u5df2\u4e0d\u518d\u88ab\u5e7f\u6cdb\u4f7f\u7528\u3002.<\/p>\n

\u954d\u78b3\u9170\u662f\u954d\u5316\u5b66\u9886\u57df\u8fc4\u4eca\u53d1\u73b0\u7684\u6700\u5371\u9669\u7269\u8d28\u4e4b\u4e00\uff0c\u5176\u6bd2\u6027\u6781\u9ad8\uff0c\u4e14\u5177\u6709\u9ad8\u6325\u53d1\u6027\u548c\u5feb\u901f\u76ae\u80a4\u5438\u6536\u7279\u6027\u3002\u5728\u9ed1\u5e02\u4e0a\u8d2d\u4e70\u954d\u78b3\u9170\u3002.<\/p>\n

\"\u6bd2\u836f\u5546\u5e97\"<\/p>\n

\u7ed3\u6784\u4e0e\u952e\u5408<\/span><\/h2>\n

\u5728\u56db\u7fb0\u57fa\u954d\u4e2d\uff0c\u954d\u7684\u6c27\u5316\u6001\u88ab\u8bbe\u5b9a\u4e3a\u96f6\u3002\u8be5\u5206\u5b50\u5f0f\u7b26\u540818\u7535\u5b50\u89c4\u5219\u3002 \u8be5\u5206\u5b50\u5448\u56db\u9762\u4f53\u7ed3\u6784\uff0c\u914d\u6709\u56db\u4e2a\u7fb0\u57fa\uff08\u4e00\u6c27\u5316\u78b3\uff09\u914d\u4f53\u3002\u901a\u8fc7\u7535\u5b50\u884d\u5c04\u7814\u7a76\u6d4b\u5f97Ni\u2013C\u548cC\u2013O\u952e\u8ddd\u5206\u522b\u4e3a1.838(2)\u548c1.141(2)\u57c3\u3002\u5728\u7ebf\u8d2d\u4e70\u954d\u7fb0\u57fa\u5316\u5408\u7269\u3002.<\/p>\n

\u51c6\u5907<\/span><\/h3>\n

\u954d(CO)\u2084\u9996\u6b21\u7531\u8def\u5fb7\u7ef4\u5e0c\u00b7\u8499\u5fb7\u4e8e1890\u5e74\u901a\u8fc7\u954d\u91d1\u5c5e\u4e0e\u4e00\u6c27\u5316\u78b3\u7684\u76f4\u63a5\u53cd\u5e94\u5408\u6210\u3002\u8fd9\u9879\u5f00\u521b\u6027\u5de5\u4f5c\u9884\u793a\u4e86\u591a\u79cd\u5176\u4ed6\u91d1\u5c5e\u7fb0\u57fa\u5316\u5408\u7269\u7684\u5b58\u5728\uff0c\u5305\u62ec\u4e94\u4ef7\u9492\u3001\u94ec\u3001\u9530\u3001\u94c1\u548c\u94b4\u7684\u7fb0\u57fa\u5316\u5408\u7269\u3002\u8be5\u5316\u5408\u7269\u572819\u4e16\u7eaa\u672b\u8fd8\u88ab\u5de5\u4e1a\u5e94\u7528\u4e8e\u954d\u7684\u63d0\u7eaf\u3002.<\/p>\n

\u5728323 K\uff0850 \u00b0C\uff1b122 \u00b0F\uff09\u4e0b\uff0c\u5c06\u4e00\u6c27\u5316\u78b3\u901a\u5165\u4e0d\u7eaf\u954d\u4e2d\u3002\u6700\u4f73\u53cd\u5e94\u901f\u7387\u51fa\u73b0\u5728130 \u00b0C\u3002\u5728\u9ed1\u5e02\u4e0a\u8d2d\u4e70\u954d\u919b\u3002.<\/p>\n

\u70ed\u8131\u7fb0\u5316<\/span><\/h4>\n

\u5728\u9002\u5ea6\u52a0\u70ed\u4e0b\uff0cNi(CO)4<\/sub> \u5206\u89e3\u4e3a\u4e00\u6c27\u5316\u78b3\u548c\u91d1\u5c5e\u954d\u3002\u7ed3\u5408\u5176\u6613\u4eceCO\u53ca\u6781\u4e0d\u7eaf\u954d\u4e2d\u751f\u6210\u7684\u7279\u6027\uff0c\u8fd9\u79cd\u5206\u89e3\u53cd\u5e94\u6784\u6210\u4e86\u8499\u5fb7\u6cd5\uff08\u7528\u4e8e\u5728\u7ebf\u8d2d\u4e70\u954d\u78b3\u9170\u6216\u8868\u9762\u9540\u5c42\uff09\u7684\u57fa\u7840\u3002\u70ed\u5206\u89e3\u59cb\u4e8e180\u2103\u9644\u8fd1\uff0c\u5e76\u968f\u6e29\u5ea6\u5347\u9ad8\u800c\u52a0\u5267\u3002.<\/p>\n

\"\u751f\u7269\u6b66\u5668\"<\/p>\n

\u5728\u7ebf\u8d2d\u4e70\u954d\u78b3\u9170<\/h3>\n

\u4e0e\u4eb2\u7535\u8bd5\u5242\u548c\u6c27\u5316\u5242\u7684\u53cd\u5e94<\/span><\/h5>\n

\u954d\u78b3\u9170\u5316\u7269\u53ef\u88ab\u6c27\u5316\u3002\u6c2f\u6c14\u5c06\u954d\u78b3\u9170\u5316\u7269\u6c27\u5316\u4e3aNiCl\u30022<\/sub>, \u91ca\u653e\u4e00\u6c27\u5316\u78b3\u6c14\u4f53\u3002\u5176\u4ed6\u5364\u7d20\u7684\u53cd\u5e94\u673a\u5236\u4e0e\u6b64\u7c7b\u4f3c\u3002\u8be5\u53cd\u5e94\u4e3a\u6c89\u6dc0\u6709\u6bd2\u5316\u5408\u7269\u4e2d\u7684\u954d\u7ec4\u5206\u63d0\u4f9b\u4e86\u4fbf\u6377\u65b9\u6cd5\u3002.<\/p>\n

Ni(CO)\u7684\u53cd\u5e944<\/sub> \u4e0e\u70f7\u57fa\u548c\u82b3\u57fa\u5364\u5316\u7269\u53cd\u5e94\u5e38\u751f\u6210\u7fb0\u57fa\u5316\u6709\u673a\u4ea7\u7269\u3002.<\/p>\n

\u4e59\u70ef\u57fa\u5364\u5316\u7269\uff08\u5982PhCH=CHBr\uff09\u7ecfNi(CO)\u5904\u7406\u540e\u8f6c\u5316\u4e3a\u4e0d\u9971\u548c\u916f\u30024<\/sub> \u968f\u540e\u52a0\u5165\u7532\u9187\u94a0\u3002.<\/p>\n

\u6b64\u7c7b\u53cd\u5e94\u5f88\u53ef\u80fd\u4e5f\u901a\u8fc7\u6c27\u5316\u52a0\u6210\u9014\u5f84\u8fdb\u884c\u3002\u70ef\u4e19\u57fa\u5364\u5316\u7269\u53ef\u751f\u6210\u03c0-\u70ef\u4e19\u57fa\u954d\u5316\u5408\u7269\uff0c\u4f8b\u5982\uff08\u70ef\u4e19\u57fa\uff092<\/sub>\u4f602<\/sub>Cl2<\/sub>:<\/p>\n

\n
2 Ni(CO)4<\/sub>\u00a0+ 2 ClCH2<\/sub>CH=CH2<\/sub>\u00a0\u2192 Ni2<\/sub>(\u03bc<\/i>-Cl)2<\/sub>(\u03b7<\/i>3<\/sup>-C3<\/sub>H5<\/sub>)2<\/sub>\u00a0+ 8 \u6c27\u5316\u78b3<\/dd>\n<\/dl>\n

\"\u6bd2\u836f\u94fa\"<\/p>","protected":false},"excerpt":{"rendered":"

Melting point: :<\/b>-19\u00b0C
\nBoiling point: :<\/b>43\u00b0C
\nDensity\u00a0 :<\/b>1,32 g\/cm3<\/sup>
\nvapor pressure\u00a0 :<\/b>321 mmHg at 20 \u00b0C
\nFlash point: :<\/b><-20\u00b0C
\nform\u00a0 :<\/b>liquid
\ncolor\u00a0 :<\/b>colorless
\nOdor :<\/b>Sooty odor detectable at 0.5 to 3 ppm
\nWater Solubility\u00a0 :<\/b>soluble in ~5000 parts air free H2O; soluble alcohol, benzene, chloroform, acetone, CCl4 [MER06]
\nSensitive\u00a0 :<\/b>heat sensitive
\nExposure limits :<\/b>TLV-TWA: 0.05 ppm (0.35 mg as Ni\/m3<\/sup>) (ACGIH)
\nPEL: 0.001 ppm (0.007 mg Ni\/m3<\/sup>) (OSHA, MSHA and NIOSH)
\nIDLH: 0.001 ppm (NIOSH, OSHA).\u00a0Stability: :<\/b>Stable. Highly flammable and highly reactive. Explosion hazard.
\nEPA Substance Registry System :<\/b>Nickel carbonyl (13463-39-3)<\/p>\n","protected":false},"featured_media":343,"comment_status":"open","ping_status":"closed","template":"","meta":[],"product_brand":[],"product_cat":[17],"product_tag":[],"class_list":{"0":"post-342","1":"product","2":"type-product","3":"status-publish","4":"has-post-thumbnail","6":"product_cat-poisons-for-sale","8":"first","9":"instock","10":"shipping-taxable","11":"purchasable","12":"product-type-variable"},"_links":{"self":[{"href":"https:\/\/poisonshops.com\/zh\/wp-json\/wp\/v2\/product\/342","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/poisonshops.com\/zh\/wp-json\/wp\/v2\/product"}],"about":[{"href":"https:\/\/poisonshops.com\/zh\/wp-json\/wp\/v2\/types\/product"}],"replies":[{"embeddable":true,"href":"https:\/\/poisonshops.com\/zh\/wp-json\/wp\/v2\/comments?post=342"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/poisonshops.com\/zh\/wp-json\/wp\/v2\/media\/343"}],"wp:attachment":[{"href":"https:\/\/poisonshops.com\/zh\/wp-json\/wp\/v2\/media?parent=342"}],"wp:term":[{"taxonomy":"product_brand","embeddable":true,"href":"https:\/\/poisonshops.com\/zh\/wp-json\/wp\/v2\/product_brand?post=342"},{"taxonomy":"product_cat","embeddable":true,"href":"https:\/\/poisonshops.com\/zh\/wp-json\/wp\/v2\/product_cat?post=342"},{"taxonomy":"product_tag","embeddable":true,"href":"https:\/\/poisonshops.com\/zh\/wp-json\/wp\/v2\/product_tag?post=342"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}